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Exploring the Thermal Conductivity and Heat Transfer Potential of Nanorefrigerants using the Hot Disk TPS

The development of safe and affordable refrigeration changed the way that people live and eat. Research and development on refrigeration systems has been continuous; researchers working to make refrigerators more efficient have cut their power requirements by 75% in the last 40 years. Refrigerants are a crucial component in refrigeration systems, they help to remove heat from one area and transfer and expel it in another by changing between a liquid and gaseous state. In the past decade, researchers have been studying the potential of nanofluids to raise the thermal conductivity of many different liquids, refrigerants being one of them. By adding nano sized particles with a high thermal conductivity to a host refrigerant, researchers hope to obtain a nanorefrigerant with a much higher thermal conductivity that can be used to increase the efficiency of the overall refrigeration system. Jiang et al. (2009) added carbon nanotubes (CNTs) of varying diameter sizes and aspect ratios to the refrigerant R113 to determine if they have the potential to create an efficient nanorefrigerant.

Thermal Conductivity Applications Refrigerant Use

Figure 1. Air conditioners1 and refrigerators2 are two of the most common applications for refrigerants that have made life more comfortable and convenient.

Jiang et al. (2009) chose to use CNT’s in their research as they have a high thermal conductivity and therefore had the potential to produce a good quality nanorefrigerant. Previous studies had used metal and metal oxide nanoparticles, both of which have lower thermal conductivity values than CNTs. As the researchers wanted to find the best possible CNT for use in this field, they used four CNTs of varying size and aspect ratios to create different four nanorefrigerants for testing. Each of the four nanorefrigerants had mixtures created with varying volume fractions of CNTs. 

Jiang et al. (2009) used the Hot Disk TPS Thermal Constants Analyzer to measure the thermal conductivity of each of their CNT-refrigerant mixtures. The Hot Disk TPS uses a thin nickel foil and Kapton insulated probe as both the heating element and the temperature sensor during testing. Jiang et al. (2009) placed the Hot Disk probe vertically into each mixture, and the resistance change with time of the probe was used to determine the thermal conductivity of each sample. It is good practice to take multiple measurements on the same sample. In order to compare the efficiency of CNTs to other options, the thermal conductivities of several CNT-water nanofluids and nanorefrigerants made using metal and metal oxide nanoparticles were also tested. For those interested in the thermal conductivity testing of liquids, a liquid sample cell is also available for use with the TPS system and probe (Figure 2). This consists of a small sample holder which seals 2-3 ml of the liquid to be tested around the sensor. This sample holder is ideal for thermal conductivity measurements on highly expensive fluids as it only requires a small volume for accurate testing. The set up of the liquid cell means that it obtains maximum probing depth for a small amount of liquid.

Thermal Conductivity Applications Liquid Cell Internal And Loading Comp (1)

Figure 2. The liquid cell available for use with the Hot Disk TPS when testing liquid samples. The Hot Disk sensor is sealed in the middle of cell surrounded by the liquid to be tested.

Results obtained using the Hot Disk TPS thermal conductivity instrument indicated that the thermal conductivity of the CNT-nanorefrigerants increased with the volume fraction of nanoparticles added. Diameter and aspect ratio both had an impact on the magnitude of the increase, a smaller diameter nanoparticle created a nanorefrigerant with a higher thermal conductivity, while a larger aspect ratio also contributed positively to thermal conductivity. Overall, Jiang et al. (2009) determined that diameter had a larger impact than aspect ratio. CNTs were determined to be more effective at raising the thermal conductivity of refrigerants than other nanoparticles, as the thermal conductivities of the CNT nanorefrigerants were much higher than those created with metal and metal oxide particles. 

With this study, Jiang et al. (2009) were able to prove the efficacy of using carbon nanotubes as a means of increasing the efficiency of a refrigerant. By comparing several different CNTs, they also determined that diameter has an important impact on the effect that the CNT will have. Work such as this has the potential to be the next step forward in improving the energy efficiency of our refrigeration systems. This study encourages future work studying the effect of adding CNTs to different refrigerants to create an environmentally friendly nanorefrigerant with excellent thermal transport capabilities. 

Note: For comprehensive results and an in depth discussion, please follow the link to this scientific paper in the reference section

Learn More About Hot Disk Transient Plane Source (TPS)

The Hot Disk Transient Plane Source (TPS) technique allows for precise thermal conductivity measurement of a huge array of materials ranging in thermal conductivity from 0.005 to 1800 W/m∙K . TPS is capable of measuring bulk and directional thermal properties of solids, liquids, pastes and powders.

References:

Hoffman, P. Basic Refrigeration Cycle. Ag Power Web Enhanced Course Materials (Online). Available at: https://www.swtc.edu/ag_power/air_conditioning/lecture/basic_cycle.htm 

Jiang, W., Ding, G., Peng, H. 2009. Measurement and model on thermal conductivities of carbon nanotube nanorefrigerants. International Journal of Thermal Sciences. 48: 1108-1115.  Available at : http://www.sciencedirect.com/science/article/pii/S1290072908002494 

Risser, R. 2011. The Proof is in the Pudding: How Refrigerator Standards Have Saved Consumers $Billions. US Department of Energy (Online). Available at: http://www.energy.gov/articles/proof-pudding-how-refrigerator-standards-have-saved-consumers-billions 

http://www3.epa.gov/ozone/title6/phaseout/22phaseout.html 

Photo References: 

1- http://aggroupasia.com/?page_id=874 

2- http://www.whirlpool.com/kitchen-1/refrigeration-2/refrigerators-3/102110023/ 

A selection of links to refrigerant producers and distributors: 

http://www.refrigerants.com/ 

https://www.chemours.com/Refrigerants/en_US/ 

http://www.honeywell-refrigerants.com/

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