Application Select

Determining the Thermal Conductivity of a Fire Protective Coating at Elevated Temperatures using the Hot Disk TPS 2500 S

Fire resistance and protection are crucial elements of building design. Fire protection can be incorporated into structures both actively and passively; active fire protection measures include smoke alarms and sprinkler systems, while passive measures comprise of protective coatings on structural components, incorporating fire resistant materials into construction, and compartmentalizing the building layout. Protective coatings are designed to swell to form an insulating, protective layer between the steel structure and the fire to prevent it from heating to the point that it loses structural strength and can no longer support the building. These coatings save lives as they increase the amount of time available for evacuations and fire fighters to combat the blaze. Low thermal conductivity is an essential characteristic of these products. In 2013, Gardelle et al. undertook a study to create a protective coating that would outperform intumescent paint (Figure 1), the current industry favorite, by adding expandable graphite (EG) to a curable silicone based coating.

Thermal Conductivity Applications Intumescent Paint Steel

Figure 1. Illustration depicting how intumescent paint expands during a fire to provide an insulating barrier between the steel and the flame1.

Gardelle et al. (2013) created their EG/silicone coating by adding various amounts (5-25%) of expandable graphite at 5% intervals to a silicone resin. Samples of intumescent paint of the same size were also prepared for use as a reference. In order to study the performance of their product during a hydrocarbon fire, the team used a furnace performing at the UL1709 standard to stimulate the conditions. The critical temperature at which steel loses 60% of its original strength and can no longer support a regular structural loading is 500°C. 400°C is considered to be the critical temperature for a steel structure under heavy loading. The team measured the length of time it took for the steel to reach each critical temperature with the addition of each EG/S1 coating as a protective layer. The rate and velocity of expansion were measured to determine how the compound performed compared to intumescent paint.

Elevated Temperature Thermal Conductivity Testing

Analysis of thermal conductivity was a crucial component of this project, as the thermal properties of the compound would determine how much heat the steel was exposed to during the test, and how quickly it would heat to the critical temperature. The Hot Disk Transient Plane Source 2500 S was used for thermal conductivity testing of the 25% EG/S1 coating along a temperature range from 25-500°C (Figure 2). The TPS 2500 S is a state of the art instrument that measures thermal conductivities from 0.005 W/mK to 1000 W/mK and can perform measurements at temperatures up to 1000°C. A variety of products, including furnaces and heat proof cables, are available from Thermtest to facilitate high temperature testing needs.

Thermal Conductivity Applications Furnace Testing Set Up

Figure 2. Set up that can be used for high temperature testing with the Hot Disk TPS. The Hot Disk sensor is sandwiched between two sample pieces. More than one sample can be tested at a time.

Expansion and Thermal Conductivity at Elevated Temperatures

Tests performed by Gardelle et al. (2013) revealed that the coating that they had developed did work to protect the steel from high temperatures, and outperformed intumescent paint. The sample containing 25% EG expanded by an impressive 3400%, 2x that of intumescent paint. The thermal conductivity of the coating decreased as it expanded as the temperature rose, the final thermal conductivity measured at 500°C was 0.35 W/mK. As a result of this low thermal conductivity, heat will be transferred from the fire to steel less quickly.

Gardelle et al. (2013) concluded that the 25% EG/S1 protective coating they developed had the low thermal conductivity and large expansion rate to perform well as a fire resistant material and would help protect steel from losing structural strength in high temperatures. The ability of the Hot Disk TPS thermal conductivity testing system to effectively measure thermal properties at high temperatures makes it a good choice for research such as this where thermal conductivity measurement at elevated temperatures is a critical element for project success.

Note: For comprehensive results and a full discussion, please follow the link to this scientific paper in the reference section.

Learn More About Hot Disk Transient Plane Source (TPS)

The Hot Disk Transient Plane Source (TPS) technique allows for precise thermal conductivity measurement of a huge array of materials ranging in thermal conductivity from 0.005 to 1800 W/m∙K . TPS is capable of measuring bulk and directional thermal properties of solids, liquids, pastes and powders.

References:

Frater, G., Kleinfeldt, C. 2011. Fire Protection of Steel Structures – Acceptable and Alternative Solutions. Advantage Steel. 39. 16-21. 
PDF available at:  http://www.cisc-icca.ca/getmedia/cd5b227d-8401-4805-8345-40433f563cfe/advantage39_1.aspx?ext=.pdf 

Gardelle, B., Duquesne, S., Vandereecken, P., Bourbigot, S. 2013. Characterization of the carbonization process of expandable graphite/silicone formulations in a simulated fire. Polymer Degradation and Stability. 98(5):1052–1063.  
Available at: http://www.sciencedirect.com/science/article/pii/S0141391013000268 

Phan, L.T., McAllister, T.P., Gross, J.L., Hurley, M.J.  2010. NIST Technical Note 1681: Best Practice Guidelines for Structural Fire Resistance Design of Concrete and Steel Buildings. National Institute of Standards and Technology.  
PDF available at: http://nvlpubs.nist.gov/nistpubs/technicalnotes/nist.tn.1681.pdf 

Photo References: 

1- http://www.astroflame.com/intumescent-paint-steel.html 

A selection of fire protective coating manufacturers: 

http://www.firefree.com/ 

http://www.flamecontrol.ca/fire-retardant-coating/product-list/ 

http://contegointernational.com/

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