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Author(s): Amy S. Fleischer, Ronald J. Warzoha

Keywords: aspect ratio, carbon nanotubes, cnts, composite, density, diameter, fillers, interfacial thermal resistance, length, pcms, phase change materials, thermal conductivity, thermal diffusivity, tps device, transient plane source, transient plane source (tps) device

Abstract: The thermal conductivities of four composite paraffin phase change materials (PCMs) containing embedded multi-walled carbon nanotubes (MWCNTs) with varying dimensions were determined. The goals of this study were to investigate the interfacial thermal resistance between two MWCNTs, and to investigate the ballistic and diffusive components of the thermal resistance at the interface. It was found that the thermal conductivity of the composite PCMs increased with the diameter of the MWCNT used as filler. This result was unexpected, as smaller nanotubes usually have a higher thermal conductivity. It was determined that larger diameter nanotubes have less interfacial thermal resistance due to a decrease in ballistic phonon scattering that occurs as a result of the increased contact area between the nanotubes.

Reference: Applied Energy, 154 (2015) 271-276

DOI: 10.1016/j.apenergy.2015.04.121