The thermoelectric properties of the Ca1-xGdxMnO3-delta system where x= 0.00, 0.02, and 0.05 were evaluated. It was determined that the sample with the lowest electrical resistivity was the Ca0.95Gd0.05MnO3-delta sample. This result was attributed to the increase content of Mn3+ in the Mn4+ matrix resulting from doping of gadolinium. The dominant charge carriers in all samples were holes, as the thermopower was negative. The highest thermoelectric figure of ...
The partial replacement of Ca2+ ions with Eu3+ in the Ca3Co3.95Ga0.05O9+delta system to give polycrystalline samples of Ca3-xEuxCo3.95Ga0.05O9+delta (x = 0.00, 0.02, and 0.10) was performed in order to assess the effect that the dopant had on thermoelectric properties of this system. It was found that the electrical resistivity and thermopower increased with increasing Eu3+ content, and the thermal conductivity decreased. The highest thermoelectric figure of ...
The partial replacement of Ca2+ ions with Eu3+ in the Ca3Co3.95Ga0.05O9+delta system to give polycrystalline samples of Ca3-xEuxCo4O9+delta (x = 0.00, 0.05, and 0.10) was performed in order to assess the effect that the dopant had on thermoelectric properties of this system. It was found that the electrical resistivity and thermopower increased when Eu3+ is added, and the thermal conductivity decreased. The highest thermoelectric figure of merit ...
Single phase, orthohombic structured Ca0.98Bi0.02Mn1−xSixO3−delta (x = 0.00, 0.02 and 0.03) samples were prepared using solid state reaction. The authors investigated whether they could improve the thermoelectric properties of the product by substituting calcium and manganese with bismuth and silicon, respectively. The resulting products had an increase in electrical resistivity and thermopower and a decrease in thermal conductivity as the amount of silicon added increased. Magnetic moments decreased in the ...
The thermoelectric and magnetic properties of the Ca3Co4-xCuxO9+delta system where x = 0, 0.05, 0.07, 0.10, and 0.15 were investigated as materials of this type have potential for use in thermoelectric generators. The goal of this work was to identify the sample in this system having the highest thermoelectric figure of merit. To accomplish this, a high thermopower, a high thermal voltage, a low resistivity, and a low thermal conductivity were required. It ...
