This article investigated new macro-cellular carbons, called carbon meringues, formed by whipping an aqueous solution of tannin until liquid foam is obtained. Carbon meringues were fully investigated, and thermal conductivity was analyzed using a transient plane source method. Thermal conductivity of carbon meringues was found to be slightly higher than that of tannin-based CVC foams of low density. Carbon meringues maintained higher mechanical strength in the same range of density....
Author(s): A. Szczurek, Alain Celzard, Antonio Pizzi, M. Stauber, V. Fierro
Porous monoliths, often referred to as polymerised High Internal Phase Emulsions (polyHIPEs), are materials made of polymers that have applications ranging from chemical engineering to biomedicine. In this paper, a TPS instrument measured the thermal conductivity of tannin-based monoliths with the transient plane source (TPS) technique. Results showed that as the porosity of the polyHIPEs increased, the thermal conductivity decreased linearly, a characteristic that could be used for applications in ...
Author(s): A. Pizzi, Alain Celzard, Alicia MartC-nez de Yuso Arisa, Alicia Martinez de Yuso, Andrzej Szczurek, Antonio Pizzi, Vanessa Fierro
Seasonal thermal storage based on phase change materials (PCMs) require a thermally conductive host because they typically have low thermal conductivities. In this study, tannin-based composite carbon foams were prepared using thermally conductive exfoliated graphite (EG) fillers and pMDI additives. A thermal analyzer measured the thermal conductivity of the samples using the transient plane source (TPS) method. Results showed that the EG-carbon foams and the EG/pDMI-carbon foams showed significantly ...
Author(s): Alain Celzard, Antonio Pizzi, P. Jana, V. Fierro
Tannin and lignin are organic materials that are more cost-effective than synthetic, non-renewable phenolic compounds. In this paper, tannin-lignin-formaldehyde (TLF) composites were used to synthesize thermally insulative mesoporous aerogels. A thermal analyzer measured the thermal conductivity of two TLF samples using the transient plane source (TPS) method. Results showed that the TLF aerogels had better thermal insulation properties than any other organic aerogels reported in the literature, and were well ...
Author(s): A. Szczurek, Alain Celzard, Antonio Pizzi, B. N. Kuznetsov, G. Amaral-Labat, L. I. Grishechko, V. Fierro
This paper examined the synthesis of hyperbranched polymers (HBPs) and how their hydroxyl end groups help form networks in tannin-based foams. A thermal analyzer (TPS) measured the thermal conductivity of the foam samples using the transient plane source (TPS) method. Results showed that modified foams retained their thermal insulation properties even with the addition of oligomeric precursors. This gives good indication that the addition of hydroxyl-terminated oligomeric precursors to tannin ...
Author(s): Alain Celzard, Antonio Pizzi, D. Le Nouen, H. A. Essawy, K. Rode, L. Delmotte, V. Fierro, X. Li
