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Author(s): , ,

Keywords: , , , , , , , ,

Abstract: The low-temperature thermoelectric properties of Ca3-xYbxCo4O9+delta systems (x = 0, 0.02, 0.05, and 0.10). It was determined that these systems produced positive thermopower, indicating that the dominant carriers were holes. The electrical resistivity and thermopower were found to increase with increasing Yb3+ content, and the thermal conductivity was found to decrease. The highest calculated thermoelectric figure of merit was 0.037, and this was calculated for the Ca2.95Yb0.05Co4O9+delta sample.

Reference: Ceramics International 40 (2014) 5937–5943

DOI: 10.1016/j.ceramint.2013.11.040